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Esters phosphoriques, phosphonates et oxydes de phosphine dérivés de sucres. Communication préliminaire

✍ Scribed by Jean M. J. Tronchet; Jean-Richard Neeser; Etienne J. Charollais

Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
165 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis

Some sugar phosphates, phosphonates and phosphine oxides, Preliminary communication

Some new phosphates of 1, 2‐O‐isopropylidene‐α‐D‐ribofuranose have been prepared. Reactions of 3‐C‐cyanomethylidene‐3‐deoxy‐1, 2‐O‐isopropylidene‐5‐O‐trityl‐α‐D‐erythro‐pentofuranose (9) have been studied. On treatment with phosphorus nucleophiles, 9 led to phosphorus bearing branched‐chain sugar derivatives. Branched‐chain cyanosugars as 15 and 16 prepared by cis‐vic‐dihydroxylation of 9 constitute interesting potential precursors of new types of cyclic sugar phosphates.

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