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Esters and amides from aziridine 2-carboxylic acid salts

✍ Scribed by C. Lambert; H.G. Viehe

Book ID
104222192
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
188 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

Potassiiim salts of azlridlne-A 7-carboxylic acid derivatives are efficiently converted into esters of amides by reactions with alkyl halides, alkyl ditwliJLs or by acyiatiorl with trimethylacetyl chloride followed by aminolyss.

Azlrjdlnc be,r,gs to a class of alkylatlng compounds of Importance in industry as well li as in biology

The actlvlty of its derlvatlves 1s modulated by the l-lng substituents. In

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The halohydrins prepared from epoxide esters, were treated with hydroxylamine derivatives. In subsequent reaction with NaOH/K 2 CO 3 /Bu 4 NHSO 4 the N-protected b-halo a-aminoesters thus obtained were converted into N-hydroxy ariridine 2-carboxylic esters in good yields.