Esterification of peptides in aqueous solution
โ Scribed by Osamu Yonemitsu; Tatsuo Hamada; Yuichi Kanaoka
- Book ID
- 104239348
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 104 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract The synthesis of a variety of cyclic peptides from __N__โphthaloylโprotected diโ, triโ, tetraโ, and pentapeptides with different aminocarboxylic acid tethers by photodecarboxylation โ initiated by intramolecular electron transfer โ has been explored in aqueous media. The progress and th
## Abstract Oligopeptideโmediated helix stabilization of peptides in hydrophobic solutions was previously found by NMR and CD spectroscopic studies. The oligopeptide included the hydrophobic amino acids found in its parent peptide and were interposed by relevant basic or acidic amino acids. The str
A convenient esterification reaction of poly(methacry1ic acid) (PMAA) with certain alkyl halides was performed using 1,8-diazabicyclo-[5.4.0] -7-undecene (DBU) as a base in aqueous solution or in water. The esterification reaction of PMAA with propargyl bromide (PB) proceeded very smoothly and quant