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Ester cleavage by a phenolic quaternary phosphonium surfactant

✍ Scribed by Jaeger, David A.; Bolikal, Durgadas


Book ID
126987518
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
441 KB
Volume
51
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Enantioselective cleavage of esters by h
✍ Marco C. Cleij; Wiendelt Drenth; Roeland J. M. Nolte πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 651 KB

## Abstract Cleavage of chiral __p__‐nitrophenyl esters derived from the amino acid phenylalanine by histidine‐containing tripeptides has been studied in micellar solutions of four quaternary ammonium surfactants. Enzyme‐like enantioselectivities up to __k__~__I__~/__k__~__D__~ = 131 (at 0Β°C) are o