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ESR study on the .sigma.- and .pi.-radical cations formed by one-electron oxidation of phenyldiazomethanes

✍ Scribed by Ishiguro, Katsuya; Sawaki, Yasuhiko; Izuoka, Akira; Sugawara, Tadashi; Iwamura, Hiizu


Book ID
126302294
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
245 KB
Volume
109
Category
Article
ISSN
0002-7863

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Determination, by ESR Spectroscopy, of t
✍ Prof. K. Dimroth; Dr. N. Greif; Dipl.-Chem. W. StΓ€de; Dr. F. W. Steuber πŸ“‚ Article πŸ“… 1967 πŸ› John Wiley and Sons 🌐 English βš– 211 KB πŸ‘ 1 views

one obtains the electronegativity XNSF, = 3.3. If one plots the mean P F frequency of the phosphoryl halides against the sum of the electronegativities, one obtains a linear dependence, whence the electronegativity of the NSF2 group again appears as 3.3. Compound (4) IS a clear liquid of b.p. 7 2 Β°C