𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ESR. Study of the Pentacoordinated Arsenic Radical Anion [(OH)3(O)AsCH2As(O)(OH)2]=

✍ Scribed by Michel Geoffroy; Antoine Llinares; John R. Morton

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
163 KB
Volume
66
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The anion [(OH)~3~(O)AsCH~2~As(O)(OH)~2~] has been trapped in an X‐irradiated single crystal of methylene diarsonic acid. The g‐tensor and the hyperfine coupling tensors of the two ^75^As‐nuclei have been obtained and the spin densities in the arsenic 4s‐ and 4p‐orbitals determined.

📜 SIMILAR VOLUMES

Variational transition-state theory stud
Variational transition-state theory study of the atmospheric reaction OH + O3 → HO2 + O2
✍ Li-Ping Ju; Ke-Li Han; António J. C. Varandas 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 1 views

## Abstract We report variational transition‐state theory calculations for the OH + O~3~→ HO~2~ + O~2~ reaction based on the recently reported double many‐body expansion potential energy surface for ground‐state HO~4~ [Chem Phys Lett 2000, 331, 474]. The barrier height of 1.884 kcal mol^−1^ is comp

Salts with the Triborate Anion [B3O3F2(O
Salts with the Triborate Anion [B3O3F2(OH)2]–: A Combined Experimental and Theoretical Study
✍ Maik Finze; Guido J. Reiss 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

## Abstract Reactions of [3‐NC‐B~11~F~10~]^2–^ with aqueous bases resulted in a cluster degradation. From the reaction mixtures, salts of the [B~3~O~3~F~2~(OH)~2~]^–^ anion (1) with [Ph~4~P]^+^ or [Ph~3~MeP]^+^ as countercations were isolated. Both salts were investitgated by single‐crystal X‐ray d

Initial distribution of vibration of the
Initial distribution of vibration of the OH radicals produced in the H + O3 → OH(X2Π1/2,3/2) + O2 reaction. Chemiluminescence by a crossed beam technique
✍ H. Ohoyama; T. Kasai; Y. Yoshimura; H. Kimura; K. Kuwata 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 334 KB

The cherniluminescence in the H+ 0, -OH(X \*lIIW,& +O, reaction was observed uvng a crossed beam tcebnlqu& l%e tnilial population of the OH radicals tn the vibratIonal slate v (4 < u UG 9) were found to be N( 9) -1.0, N(B) -0.95&O 1, N(7) -0.9kO.2, N(6) -0 2\*0 1 and N(5) -N(4) -0 2&O 2 The IOEII cr