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ESR study of the kinetics of H/D exchange in the 5-hydroxypyrimidine series

โœ Scribed by V. P. Lezina; M. M. Borunov; S. B. Gashev; L. D. Smirnov


Book ID
112490468
Publisher
Springer
Year
1983
Tongue
English
Weight
684 KB
Volume
32
Category
Article
ISSN
1573-9171

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Proton nmr spectroscopy is used to measure the deuterium exchange rates of C8 protons in individual purines of the dodecamer 5'-d( CGCGAATTCGCG) -3' and their temperature dependence. In perfect agreement with results from tritium labeling and laser Raman spectroscopy, we find that the DNA secondary