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ESR Study of Hydrogen Exchange Reaction in X-Ray-Irradiated Glycine

✍ Scribed by Larry L. Gautney, Jr. and Ichiro Miyagawa

Book ID
124629078
Publisher
Bioone
Year
1975
Tongue
English
Weight
566 KB
Volume
62
Category
Article
ISSN
0033-7587

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πŸ“œ SIMILAR VOLUMES

An ELDOR study of hydrogenβ€”deuterium exc
An ELDOR study of hydrogenβ€”deuterium exchange reactions in irradiated glycine-d2 crystals
✍ L.D. Kispert; K. Chang; T.C.S. Chen πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 362 KB

ESR and ELDOR studies of glycineill crystals irradiated at -196Β°C and warmed to 22Β°C show that the radicaIs CDzCOO-and NHSCDCOO-stable bctwecn -140Β°C and -40Β°C undergo irreversible deuterium-hydrogen exchange rcactions above -40Β°C to form the radicals CHDCOO-and CH$OO-by a step-wise decay of cD2COO-