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ESR studies on the dynamical properties of solvated copper ions

โœ Scribed by W.W. Schmidt; K.G. Breitschwerdt

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
358 KB
Volume
27
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

ESR line shape measurements of dilute Cu(NO& solutions in liquid ammonia in the temperature range 195-300 "K are reported. The line shape analysis of the four resolved copper hyperfme components indicates that the relaxation mechanisms of the electron spin mainly arise from anisotropic g and hyperfme interaction by tumbling motion and from spin-rotational interaction. A very small linewidth contribution due to unresolved 14N ligand hyperfine structure is discussed in terms of motional narrowing.

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