ESR studies of valinomycin ion pair complexes
โ Scribed by M.P Eastman; C.D Jaeger; D.A Ramirez; S.L Kelly; P.W Percival
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 433 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-2364
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## Abstract Complex formation of valinomycin with Ba^2+^ ions was investigated by circular dichroism spectroscopy. The results indicated that Ba^2+^ forms entirely different types of complexes when compared with K^+^. The data with perchlorate salt showed evidence for the formation of less stable V
Ion pairs are common species observed in the electrospray mass spectra of transition metal coordination complexes. To understand the nature of these ion pairs, a systematic study of the gas-phase chemistry of these species using ion-molecule reactions and collision-induced dissociation (CID) was car