The radical reactions of 2,6-di-t. butyl-1,4-benzoquinone with various thermally decomposing azocompounds and peroxides have been studied by ESR. On the basis of the ESR spectra of the intermediate radicals, the mechanism of the reaction is suggested. It was found that, while primary alkyl radicals
β¦ LIBER β¦
ESR studies of radical breakdown for di-t-butyl trioxide
β Scribed by Khursan, S. L. ;Shereshovets, V. V. ;Shishlov, N. M. ;Khalizov, A. F. ;Komissarov, V. D.
- Book ID
- 112684971
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 207 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0133-1736
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The copolymerization of p-tert-butoxystyrene ( TBOSt ) ( M 1 ) and di-n -butyl maleate ( DBM ) ( M 2 ) with dimethyl 2,2 -azobisisobutyrate ( MAIB ) in benzene at 60ΠC was studied kinetically and by means of ESR spectroscopy. The monomer reactivity ratios were determined to be r 1 Γ 2.3 and r 2 Γ 0