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ESR studies of n-alkane diols irradiated by γ-rays; Identification of radicals and mechanism of radical migration

✍ Scribed by Yoshimasa Hama; Katsuhiko Hamanaka; Tsunehisa Horiuchi

Publisher
Elsevier Science
Year
1979
Weight
510 KB
Volume
13
Category
Article
ISSN
0146-5724

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In addition to cyclopentenyl radicals, the ~,-irradiation of solid cyclopentadiene at 77°K results in the formation of polymeric radicals whose ESR h.f. structure has been isolated by progressive thermal annealing of glassy samples. Ultra-violet irradiation experiments suggest that the polymeric rad