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ESR studies of free radicals derived from hydroxyquinones: Naphthazarin revised - twenty-five years of the alternating linewidth effect

โœ Scribed by Ibrahim M. Ahmed; Andrew Hudson; Angelo Alberti


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
189 KB
Volume
151
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The neutral semiquinone radical obtained by photolysis of naphthazarin in THF exhibits linewidth alternation. The tempetature dependence of the ESR spectrum has been interpreted in terms of a restricted rotation of the hydroxyl groups with an activation energy of-22.7 kJ mol-'.


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