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ESR spin trapping investigation of radical formation from the reaction between hematin and tert-butyl hydroperoxide

✍ Scribed by Jolanda Van Der Zee; David P. Barr; Ronald P. Mason


Book ID
113386756
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
690 KB
Volume
20
Category
Article
ISSN
0891-5849

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Highly Selective Formation of tert-Butyl
✍ Dr. Fritz Blatter; Dr. Hai Sun; Dr. Heinz Frei πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 503 KB

Isobutane and oxygen gas loaded into zeolite BaY react upon irradiation with green or blue light to yield tert-butyl hydroperoxide in a single-photon process. This was discovered when monitoring the reaction at room temperature in situ by FT-infrared spectroscopy. Selectivity was 98%, even upon conv