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ESR spectrometry of short-lived radical pairs in solutions

✍ Scribed by Yu. N. Molin; O. A. Anisimov; R. Z. Sagdeev

Publisher
SP MAIK Nauka/Interperiodica
Year
1987
Tongue
English
Weight
943 KB
Volume
28
Category
Article
ISSN
0022-4766

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Blacetyl phosphorescence sensitzed by tnplet-excited recombmation products has been used to gwe opkally detected E!SR of radical-ton pmrs under radiolysls The yields of singlet-and tnplet-excrted products per germnate recombmmg pair of a yven muluphclty prove IO be equaI, and both are approxnnately

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## CIDNP-detactcd ESR spectra of short-hvcd radxal pairs in the photolysis of qunone (pbemzoquinon~ end duroquinone) have been sludied The infh~cnce of lhe saluraung rf-tield amplitude on the ESR spect.xa of radical pairs detected by lhis melhod hes been dcmonskucd and invatigatcd