ESR spectra of two paramametic defects in X-irradiated KCl04 are reported. it is showo tbat tbe defects can be descnbed in tenns of complexes of molecular oxygen with the Cl03 radical and the 05 radical-ion. the Γ―nteraction beΓ―ng well represented as an isotropic exchange couplmg.
ESR spectra of ClO2 and BrO2 exchange coupled to molecular oxygen
β Scribed by J.R. Byberg; J. Linderberg
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 436 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Two types of p~r3rn~~~eti~ defects in X-irr3d~~tcd KC104 and KBrO~ cryshis, one of which was pretious!y assigned to' the species CL04 and BrOq, are shown to have propcrtics characteristic of weakly bound compicses of composition [X02yOz ] and [X<Iz,20~], X = CI,Br. The bond between X02 and 02 is well represented in terms of an isotropic exchange inrcruction.
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In an effort to explore [trans-Co(en) 2 Cl 2 ] C as anion binding agent for weakly coordinating and pyramidal in shape halate ions, green coloured single crystals of [trans-Co(en) 2 Cl 2 ]ClO 3 I and [trans-Co(en) 2 Cl 2 ]BrO 3 II have been obtained by slowly mixing the separately dissolved transdic
The coupled cluster method is applied to the calculation of vibrational levels of O3 and SO1 and compared with the self consistent field approximation (SCF) and accurate quantum calculations. It is found that CCM truncated at the S4 level provides a marginally better description than SCF for the gro