𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ESR measurements of free radical photoinitiation rates by nitroxide termination

✍ Scribed by John L. Gerlock; David R. Bauer

Book ID
105335029
Publisher
Wiley (John Wiley & Sons)
Year
1984
Tongue
English
Weight
412 KB
Volume
22
Category
Article
ISSN
0887-6258

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Rate constants for the decarboxylation o
Rate constants for the decarboxylation of the t-butoxicarbonyl radical and concurring radical terminations directly obtained by kinetic ESR
✍ D. RΓΌegge; H. Fischer πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 723 KB

Rate constants of various simultaneous reactions of t-butoxicarbonyl and t-butyl radicals generated by photolysis of t-butylpivalate in n-heptane are directly determined by kinetic electron spin resonance. The temperature dependence of the decarboxylation reaction t-BuOCO + t-Bu + CO, obeys log(k/s-