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ESR “in situ” studies of photostimulated formation of benzene cation-radicals over ZSM-5 zeolites

✍ Scribed by Bolshov, V. A. ;Volodin, A. M.

Book ID
112686472
Publisher
Springer
Year
1992
Tongue
English
Weight
229 KB
Volume
46
Category
Article
ISSN
0133-1736

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✍ K.R. Cromack; D.W. Werst; M.V. Barnabas; A.D. Trifunac 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 557 KB

We have observed quadricyclane and norbomadiene radical cations in different pentasil type zeolites by EPR spectroscopy after 4 K in situ electron beam irradiation of samples in the EPR spectrometer. We report the first evidence for matrix isolation of the quadricyclane radical cation. It is stable