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ESR experiments of molecular magnet V15 at ultra-low temperatures

✍ Scribed by Takuo Sakon; Keiichi Koyama; Mitsuhiro Motokawa; Yoshitami Ajiro; Achim Müller; Bernard Barbara

Book ID
108238425
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
236 KB
Volume
346-347
Category
Article
ISSN
0921-4526

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✍ G.W. Buchanan; V.L. Webb 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 122 KB

The axial form of I5 N enriched aminocyclohexane has been detected at 173K, permitting the first direct measurement of the conformational free energy of the NH2 group. Relative intensities of individual conformer resonances in NMR spectra at low temperature, where ring inversion is estimates of the