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ESR evidence for the formation of the trimethylene padical cation -CH2CH2CH+ from cyclopropane

✍ Scribed by Xue-Zhi Qin; Ffrancon Williams

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 487 KB
Volume: 112
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)87045-1

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✦ Synopsis

Solid-state ESR studies show that the cyclopropane radical cation undergoes ring opening in the CFC12CFzQ mat&i above 80 I(. The two terminal CH, groups in the derived trimethylene radical cation are perpendicular to each other such that the electron spin is confined to one end of the molecule. the radical centre adoptins a bisected conformation very similar to that of the n-propyl radical.

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