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ESR evidence for the ferro- and antiferro-magnetic intermolecular interaction in pure and dilute mixed crystals of galvinoxyl

✍ Scribed by Kunio Awaga; Tadashi Sugano; Minoru Kinoshita


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
383 KB
Volume
128
Category
Article
ISSN
0009-2614

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✦ Synopsis


Prom the temperature dependence of ESR absorption intensity, it is shown that the intermolecular exchange interaction is ferromagnetic in the dilute mixed crystal and antiferromagnetic in the low-temperature phase of the pure crystals. The exchange energy is obtained as 2Jr= 1.5 + 0.7 meV and 2JAF= -45 z!z 2 meV on the basis of the singlet-triplet model.