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ESR evidence for halogen oxy-radical formation in the study of the heterogeneous decomposition of gaseous hydrogen peroxide in halides

✍ Scribed by M. Carlier; K. Sahetchian; L.-R. Sochet


Book ID
107731992
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
388 KB
Volume
66
Category
Article
ISSN
0009-2614

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## Abstract The unimolecular fragmentation reactions of the radical cations of diethyl, diisopropyl, dipropyl, isopropyl propyl, and di(__tert__‐butyl) peroxide have been investigated by mass spectrometric and isotopic labeling techniques. Two competing pathways for unimolecular decomposition in th