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ESR determination of the rate constant for the abstraction of chlorine from CCl4by telomeric CCl3(CH2CH2)n.(n=1–3) radicals

✍ Scribed by R. G. Gasanov; L. V. Ivanova; R. Kh. Freidlina


Book ID
112443181
Publisher
Springer
Year
1982
Tongue
English
Weight
357 KB
Volume
31
Category
Article
ISSN
1573-9171

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Abstraction of chlorine atoms from chlor
✍ R. Aloni; L. A. Rajbenbach; A. Horowitz 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 318 KB

The kinetics of chlorine transfer from CHzC12, CHC13, cc4, and CCI3CN to the triethylsilyl radical was studied in the liquid phase by a competitive method. Br abstraction from 1- bromopentane was used as a reference. The following Arrhenius parameters were determined: 40 f 0.10 1.11 f 0.18 303-343