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ESCA applied to liquids. ESCA spectra from molecular ions in solution

✍ Scribed by B. Lindberg; L. Asplund; H. Fellner-Feldegg; P. Kelfve; H. Siegbahn; K. Siegbahn


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
250 KB
Volume
39
Category
Article
ISSN
0009-2614

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✦ Synopsis


The application of ESCA IO solntions of molecular ions is described. As an example is chosen the N-methylglucamine salt of S-[p-(2-pyridylsulfan~oyl)phcnylazo] salicylic acid. It is shown that by exchange of one of th\e ions in the sohition the ESCA spectra of the individual ionic components may be deduced. For this particular case. broadening of nitrogen lines in the spectrum indicated different chemical forms in solution.


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## Abstract It is demonstrated that in a case where neither the proton nor the natural‐abundance ^13^C‐satellite spectra of a partially oriented molecule carry enough structural information, one can determine the entire molecular geometry by the combined use of several liquid crystals as solvents.