Dihydrogen, dihydride and in between: NM
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Robert H. Morris
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Article
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2008
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Elsevier Science
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English
⚖ 284 KB
Tabulating the structures and characteristic NMR properties of 17 iron complexes, 98 ruthenium complexes and 70 osmium complexes that contain dihydrogen or compressed dihydride ligands reveals a variety of trends. The H H bond lengths increase from similar Fe(II) to Ru(II) to Os(II) complexes. Iron(