Errata: [{Hg3Co(C4H6NO)6}(NO3) 2]n: A Macrobicyclic Bimetallic Chain Polymer Incorporating Deprotonated 2-Pyrrolidone Bridges
β Scribed by David M. L. Goodgame; David J. Williams; Richard E. P. Winpenny
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 272 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0044-8249
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Kurzlich haben wir uber Darstellung und Struktur des Kornplexes 1 berichtet"', der ein kationisches Birnetall-Polyrner rnit benachbarten, 32gliedrigen Makrocyclen sowie Hgund Cu-Atome elithalt, die iiber 2-Pyrrolidon-Anionen C&NO%erkniipft sind ; Gegenionen sind NO: oder Die Koordinationsgeometrie u
The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a Ο