✦ LIBER ✦

Eremophilane-Type Sesquiterpenoids from the Fermentation Broth of Plant Endophytic Fungus Pestalotiopsis photiniae Isolated from the Chinese Podocarpaceae Plant Podocarpus macrophyllus

✍ Scribed by Xiao-Long Yang; Su Zhang; Hua-Jie Zhu; Du-Qiang Luo; Xue-Yan Gao

Publisher: John Wiley and Sons
Year: 2011
Tongue: German
Weight: 192 KB
Volume: 94
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.201100010

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Two new sesquiterpenoid esters, pestalotiopins B and C (1 and 2, resp.) related to the eremophilane class, together with one known compound, berkleasmin C (3), were isolated from the fermentation broth of the plant endophytic fungus Pestalotiopsis photiniae. Their structures and relative configurations were elucidated by extensive spectroscopic analysis including 1D‐ and 2D‐NMR (HSQC, HMBC, and NOESY), and MS experiments. Compound 1 has an interesting lactam structure, and this type of sesquiterpenoid with a lactam structure is reported for the first time.

📜 SIMILAR VOLUMES

Oleanane-Type Triterpenoids from the End

Oleanane-Type Triterpenoids from the Endophytic Fungus Pestalotiopsis clavispora Isolated from the Chinese Mangrove Plant Bruguiera sexangula

✍ Du-Qiang Luo; Hui-Ying Deng; Xiao-Long Yang; Bao-Zhong Shi; Jing-Ze Zhang 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 1 views

Three new triterpenoid derivatives, named (15a)-15-hydroxysoyasapogenol B (1), (7b,15a)-7,15dihydroxysoyasapogenol B (2), and (7b)-7,29-dihydroxysoyasapogenol B (3), were isolated from cultures of the plant endophytic fungus Pestalotiopsis clavispora. Their structures and relative configurations wer