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Equilibrium Studies on Complex-Formation Reactions of Pd[(2-(2-aminoethyl)pyridine)(H2O)2]2+ with Ligands of Biological Significance and Displacement Reactions of DNA Constituents

✍ Scribed by Mohamed R. Shehata; Mohamed M. Shoukry; Fatma H. Abdel-Shakour; Rudi van Eldik


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
227 KB
Volume
2009
Category
Article
ISSN
1434-1948

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Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm