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Equilibrium studies of phosphine and amine substitution reactions of tungsten carbonyl

โœ Scribed by Angelici, Robert J.; Ingemanson, Carol M.

Book ID
127346972
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
522 KB
Volume
8
Category
Article
ISSN
0020-1669

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MNDO study of phosphine- and amine-subst
MNDO study of phosphine- and amine-substituted silicenium ions
โœ S.A. Godleski; D.J. Heacock; J.M. McKelvey ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 303 KB

MNDO calculations indicate that substituted phosphines (PR,) and amines (NR,) are capable of providing considerable stabilization to silicenium ions. Ab initio calculations have been used to survey the ability of simple first (Li + F)"' \_\_\_\_ and second row (P e C1)3 substituents to stabilize tri