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Equilibrium structures, force fields, and vibrational frequencies of titanium trihalides

✍ Scribed by N. I. Giricheva; G. V. Girichev; S. A. Shlykov


Publisher
SP MAIK Nauka/Interperiodica
Year
1992
Tongue
English
Weight
238 KB
Volume
32
Category
Article
ISSN
0022-4766

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Ab initio anharmonic force field and equ
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The quadratic, cubic, and semi-diagonal quartic force field of O@CFCl has been calculated at the MP2 level of theory employing a basis set of triple-zeta quality. The spectroscopic constants derived from the force field are in excellent agreement with those from previous and new experiments. The equ