Crystal Structure of the VV Dimer [V2O2(
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Fernando Avecilla; Carlos F. G. C. Geraldes; Anjos L. Macedo; M. Margarida C. A.
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Article
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2006
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John Wiley and Sons
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English
⚖ 238 KB
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## Abstract The behaviour of the cyclic trimeric V^V^ complex [V~3~O~3~(μ‐O)~3~(dmpp)~3~(H~2~O)](H~2~O)~2~, V~3~L~3~, (L = Hdmpp = 3‐hydroxy‐1,2‐dimethyl‐4‐pyridinone) was studied in methanol and methanol/water solutions by using ^51^V and 1D‐ and 2D ^1^H NMR spectroscopy. Red crystals, isolated fr