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Equilibrium of thecis-transisomerisation of the peptide bond with N-alkyl amino acids measured by 2D NMR

✍ Scribed by Aleksandra Misicka; Patricia M. F. Verheyden; Georges Van Binst


Publisher
Springer Netherlands
Year
1998
Tongue
English
Weight
253 KB
Volume
5
Category
Article
ISSN
1573-3149

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Synthesis of the glycosyl amino acids NΞ±
✍ Hans Paulsen; Stefan Peters; Tim Bielfeldt; Morten Meldal; Klaus Bock πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 952 KB

Two new glycosyl amino acids N'~-Fmoc-Ser[Ac4-fl-D-Galp-(1 ~ 3)-Ac2-a-D-GalN3P]-OPf p and N'~-Fmoc-Thr[Ac4-/3-D-Galp-(1 ~ 3)-Ac2-a-D-GalN3p]-OPf p were synthesized. Glycosylation of N'~-Fmoc-Ser-OPf p or N ~-Fmoc-Thr-OPfp with protected/3-o-Gal-( 1 -~ 3)-D-GaIN 3 donors afforded the glycosyl amino a