𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Equilibrium Kinetics of Chemisorption Processes

✍ Scribed by Alexander Ledovskikh; Dimitry Danilov; Peter H. L. Notten

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
211 KB
Volume
9
Category
Article
ISSN
1439-4235

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A new approach to describe the equilibrium kinetics of chemisorption is proposed. The description of the system is based on first‐principles chemical reaction kinetics and statistical thermodynamics. The rate constants are described by using a novel way of activation energy characterization. General expressions for equilibrium gas pressure isotherms and forward/backward reaction rates are obtained as a function of surface coverage. A strong influence of attraction and repulsion interaction energies between the adsorbed species on the equilibrium kinetics is found.

πŸ“œ SIMILAR VOLUMES

Equilibrium and Kinetics of NO and CO Ch
Equilibrium and Kinetics of NO and CO Chemisorptions on Nonstoichiometric Nickel–Copper Manganites
✍ Christophe Drouet; Pierre Alphonse; JosΓ© Luis GarcΔ±́a Fierro; Abel Ro πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 276 KB

The equilibrium and kinetics of adsorption of NO and CO on nonstoichiometric nickel-copper manganites have been investigated through volumetric measurements. The adsorption isotherms were satisfactorily fitted to the Freundlich equation. The equilibrium coverages at 298 K were found to depend closel

228. Kinetics of oxygen chemisorption on
228. Kinetics of oxygen chemisorption on pitch fiber
✍ P.C. Pinoli; J.G. Moncur; D.G. Mckinstry πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 130 KB

Dynamic mechanical measurements and short beam shear tests have been used to characterize an Epon 828/MPDA epoxy resin and its composites with types A and HM carbon fibers. T, of the unfilled resin is sensitive to both epoxy stoichiometry and curing schedule. Composite properties depend on fiber typ