Sunznzary. The preparation of monomcric complexes [MX(l)] is reported where 1LI. = Cu, Ag, Au; X = I, C1, 7 3 0 3 , BF4 and 1 = 2,ll-bis(diphenylphosphinomethyl)benzo[c]phenanthrene. The solution structure of the complexes is discussed on the basis of molecular weight, conductivity and NMR. measure
✦ LIBER ✦
Equilibrium Isotope Effects in Cationic Transition-Metal(I) Ethene Complexes M(C 2 X 4 ) + with M = Cu, Ag, Au and X = H, D
✍ Scribed by Schröder, Detlef; Wesendrup, Ralf; Hertwig, Roland H.; Dargel, Thomas K.; Grauel, Heidi; Koch, Wolfram; Bender, Bruce R.; Schwarz, Helmut
- Book ID
- 126227751
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 83 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0276-7333
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AbstractÐA kinetic study of the reactions of (CO) 5 CrvC(OMe)C 6 H 4 X (X4-Cl, 4-F, H, 4-Me, 4-OMe and 4-NMe 2 ) and the respective tungsten carbene complexes with primary aliphatic amines (mainly n-butylamine) in 50% MeCN±50% water (v/v) at 258C is reported. The rate law is complex and shows OH 2 a