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Equilibrium geometries of small metal clusters and their relationship to crystalline structure

โœ Scribed by B.K. Rao; S.N. Khanna; P. Jena


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
280 KB
Volume
56
Category
Article
ISSN
0038-1098

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Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi