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Equilibrium diagrams of systems O-S, O-Al, O-Cr, O-Fe, O-S-Al, O-S-Cr and O-S-Fe. Towards a thermodynamic predetermination of the circumstances of dry corrosion of metals

โœ Scribed by Prof. Dr. Ir. Marcel Pourbaix; Prof. Heming Zhang


Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
931 KB
Volume
39
Category
Article
ISSN
0947-5117

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โœฆ Synopsis


Diagrams set up as a function of an electrode potential and temperature show the conditions of thermodynamic equilibrium of all substances which may exist in the three-component systems 0-S-Al, 0-S-Cr and 0-S-Fe.

These diagrams give an overall picture of the Circumstances where, in the presence of gaseous atmospheres containing SO3, SO2 andlor sulphur vapour, aluminium, chromium and iron may be covered by a layer of oxide, sulphate or sulphide. According to some hypotheses, this may lead to a predetermination of the conditions of no-corrosion and corrosion of the metal in the presence of these atmospheres. Diagramme zeigen die Bedingungen fur das thermodynamische Gleichgewicht samtlicher Stoffe in Dreikomponentensystemen, wie 0-S-AI, 0-S-Cr und 0-S-Fe, und zwar in Abhangigkeit vom Elektrodenpotential und von der Temperatur. Diese Diagramme vermitteln einen Gesamteindruck der Bedingungen, unter welchen in Atmospharen mit SO3, SO2 und/oder Schwefeldampf Aluminium, Chrom und Eisen eine Deckschicht auf Oxid, Sulfat oder Sulfid bilden. Aufgrund yon einigen Hypothesen konnen diese Diagramme Aussagen darubei ermoglichen, ob und unter welchen Bedingungen Metal1 in Gegenwart dieser Atmospharen korrodiert wird oder nicht . * This paper is a revised version of Cebelcor's Rapports Techniques RT.266 written in French, and mentioned hereafter as reference


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