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Equilibrium constants for gas-phase ionic reactions. Accurate determination of relative proton affinities

✍ Scribed by Aue, Donald H.; Bowers, Michael T.; Webb, Hugh M.; McIver, Robert T.


Book ID
126846419
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
257 KB
Volume
93
Category
Article
ISSN
0002-7863

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For the experimental determination of the equilibrium constant of the reaction CH3 + 0 2 '5 CH302 (l), the process of methane oxidation has been studied over the temperature range of 706-786 K. The concentration of CH3O2 has been measured by the radical freezing method, and that of CH3 from the rate