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Equilibrium between 2-hydroxypyridine and 2-pyridone in the gas phase

✍ Scribed by Beak, Peter.; Fry, Fred S.

Book ID
125852320
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
408 KB
Volume
95
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

On the mechanism of proton transfer in t
On the mechanism of proton transfer in the 2-hydroxypyridine Ξ± 2-pyridone tautomeric equilibrium
✍ Martin J. Scanlan; Ian H. Hillier πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 234 KB

The saddle point for the proton transfer invohred in the equilibrium 2-hydroxypyridine = 2-pyridone has been calculated in it 3-21G basis to be 206 kJ mol-\* above the hctim form, for a unimo!ecular mechanism. This barrier is estimated to be rc-du=d to 46 kJ mol-l in the self-associated dimer.