Equilibrium and Non-equilibrium Non-stoi
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V. N. Gurin
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Article
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2002
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John Wiley and Sons
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German
โ 49 KB
Thermodynamic causes of non-stoichiometry (the so-called equilibrium non-stoichiometry) are based on the higher thermodynamic stability at T > 0 K of the non-stoichiometric composition as compared to the stoichiometric composition . Equilibrium non-stoichiometry is due to the existence of the homoge