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Equilibrium and kinetic studies of some reactions of 1-anthraquinonesulfenic acid and its methyl ester

โœ Scribed by Kice, John L.; Weclas-Henderson, Ludmilla; Kewan, Aly

Book ID
125960310
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
779 KB
Volume
54
Category
Article
ISSN
0022-3263

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โœ Tadashi Okuyama; Katsuji Miyake; Takayuki Fueno; Toshiaki Yoshimura; Shinichi So ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 483 KB

2-Methyl-2-propanesulfenic acid readily undergoes selfcondensation to give S-t-butyl 2-methyl-2-propanethiosufinate. Rates of the reaction were measured in aqueous acetonitrile solution by use o f NMR and UV spectroscopy. The reaction is second order in the substrate. The half-life in a neutral aque