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Equilibria between monohydroxo- and dihydroxo-bridged binuclear ammine rhodium(III) complexes

โœ Scribed by Christensson, Finn; Springborg, Johan

Book ID
127277738
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
540 KB
Volume
24
Category
Article
ISSN
0020-1669

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โœ John Springborg; Margareta Zehnder ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 449 KB

The reaction of the ammonia diol [(NH,)4Rh(OH)2Rh(NH,),]4' with H,O, yields among other products a peroxo-bridged dimeric species [(NH,),Rh(O,)(OH) Rh(NH,),(H,O)](ClO,),. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P2,/n and lattice