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Equatorial SO bond in 1,3-dithiane-1-oxides

✍ Scribed by M.J. Cook; A.P. Tonge

Book ID: 104246728
Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 119 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95733-8

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✦ Synopsis

The axial preference shown by the S.0 bond of thiane-l-oxide is well established' and Harpp and Gleason2 showed recently that this preference is exhibited in 1,2-dithiane-l-oxide also. Current interest3 in the effect of heteroatom X on the orientation of R in rings of type 1 prompted us to examine some 1,3-dithiane-l-oxides, and we now report 4a that the "normal" axial preference of the sulphinyl oxygen is reversed in this ring system.

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