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Equations of state: Maxwell and Van Der Waals revisited—The prediction of the volumetric properties of pure gases

✍ Scribed by Alessandro Vetere

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
846 KB
Volume
46
Category
Article
ISSN
0009-2509

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✦ Synopsis

A six-parameter equation of state is derived from fundamental relationships of thermodynamics. The proposed equation is applied to the prediction of PVT data over the entire experimental range for several gases which are representative of many molecular types including polar, non-polar and strongly associated compounds. A comparison is also given with the Lee-Kessler method. The possibility of correlating both the liquid and the supercritical range with the same set of parameters is shown for the data for 13 fluids.

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