Equations of state for fluids containing alternating heteronuclear chain molecules
โ Scribed by Dinesh Kumar Singh; K.N Khanna
- Book ID
- 103835479
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 227 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0167-7322
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โฆ Synopsis
Statistical associating fluid theory-dimer (SAFT-D) and monomer-dimer mixture theory equations of state of linear homonuclear chain are extended to fluids containing alternating heteronuclear chain molecules separately. The proposed models account for the appropriate site-site correlation functions at contact. The modified equations of state show a good agreement with generalized Flory dimer theory and MD simulation data for small and medium size ratio of hard sphere diameters.
๐ SIMILAR VOLUMES
## Abstract An equation of state for high linear polymer monolayers is discussed. It is shown that different theoretical approaches should be considered according to the range of surface concentration of the monolayer. For high dilution the theory here proposed is similar to that used in bulk solut