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Equation of state for polymers based on glass transition data

✍ Scribed by Mohammad Mehdi Papari; Reza Behjatmanesh-Ardakani; Masoumeh Kiani; Jalil Moghadasi; Antonio Campo

Publisher
Springer
Year
2011
Weight
413 KB
Volume
289
Category
Article
ISSN
0340-255X

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πŸ“œ SIMILAR VOLUMES

Equation of state and P–V–T properties o
Equation of state and P–V–T properties of polymer melts based on glass transition data
✍ M.M. Papari; M. Kiani; R. Behjatmanesh-Ardakani; J. Moghadasi; A. Campo πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 169 KB

This paper addresses a method for predicting the participating constants in equation of state (EOS) for compressed polymeric fluids using two scaling constants. The theoretical EOS undertaken is Ihm-Song-Mason (ISM), which is based on the Weeks-Chandler-Anderson (WCA), and the two constants are the

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## Abstract An equation of state for polymer melts has been devised from observation on pressure–volume–temperature data for several thermoplastics. The final equation has the form (P + Ξ  βˆ’ __mT__ ln (__cV__^\*^)) ln (__cV__^\*^) = __gT__, where __P__ is pressure; __T__, absolute temperature, __V__

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Interpenetrating polymer networks (IPN's) of poly(alky1 methacrylates) and poly-(alkyl acrylates) have been synthesized in latex form. Dynamic mechanical spectroscopy studies on these materials revealed extraordinarily broad glass transition regions, illustrating the semicompatible nature of these m