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EPR study of the free radicals in the single crystals of 2-thiothymine γ-irradiated at 300 K

✍ Scribed by Erim Bešić


Book ID
108212976
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
248 KB
Volume
917
Category
Article
ISSN
0022-2860

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EPR study of a sulfur-centered π radical
✍ Erim Bešić; Vjeran Gomzi 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 214 KB

Single crystals of 2-thiothymine (5-methyl-2-thiouracil) were c-irradiated at 77 K and studied using EPR spectroscopy. In addition to previously observed sulfur r radical, another sulfur-centered radical of p type was formed and analyzed at 100 K. The large values and the directions of the g-tensor