EPR study of selected gadolinium complexes: β-diketonates and polycarboxylates
✍ Scribed by A. Szyczewski; R. Krzyminiewski; S. Lis; J. Pietrzak; M. Elbanowski
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 294 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0969-806X
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© > ,..] " Obtained from Dojindo Company, Ltd. h Prepared by Claisen condensation of the corresponding esters and ketones with sodium amide 7. c Prepared by the condensation of ethyl trifluoroacetate and the appropriate ketone with sodium methoxide 8.
The synthesis and characterisation of an asymmetric dinuclear gadolinium(III) semiquinonato complex, namely [Gd2(HBPz3)2(dtbsq)4] CHCl3 (1; HBPz3 = hydrotris(pyrazolyl)borate, dtbsq = 3,5-di-tert-butyl-O-semiquinone), is reported. The crystal structure of 1 was determined at room temperature. It cry