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EPR studies on the role of iron in biological reactions

✍ Scribed by Daniel V Dervartanian


Publisher
Elsevier Science
Year
1973
Weight
638 KB
Volume
10
Category
Article
ISSN
0022-2364

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## Abstract The oxidation of Fe(NO)~2~(CO)~2~ by tetracyanoethylene (TCNE), by the nitrosonium ion (NO^+^), or by electrolysis in polar solvents was studied by EPR spectroscopy. A number of long‐lived (Ο„~1/2~ of the order of hours) free radicals were detected in the early stages of reaction, all ha