EPR Studies on Film Formation of Colloidal Dispersions, 1. Site Selectivity and Techniques

✍ Scribed by Sibylle E. Cramer; Gunnar Jeschke; Hans Wolfgang Spiess

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 193 KB
• Volume: 203
• Category: Article
• ISSN: 1022-1352
• DOI: 10.1002/1521-3935(20020101)203:1<182::aid-macp182>3.0.co;2-g

✦ Synopsis

Structure of the spin probes used in this work. a) Nearly spherical spin probes with a radius of approximately 350 pm. For TEMPO the p z orbital on the nitrogen atom is shown in which about 40% of the spin density is located. The z axis of the molecular frame is along the symmetry axis of this orbital, and the x axis along the N1O bond. b) Surfactant spin probes.