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EPR studies of the mechanism of intermolecular cation transfer reactions and the detection of intermediate triple and quadruplet ions

โœ Scribed by K.S. Chen; N. Hirota

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
423 KB
Volume
13
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A hew ~echankn: invohing an intermediate triple ion or ion quadruplet is suggested for intermolecular cation tr&;fer reactions in radical anions. Experimental spectra were compared with computer simulated spectra obtained ._ by solving the modified Bloch equation for the reaction M+A-+M*~'M+A-~~-~-'M++P;M~ .:,

Excellent a@em&ts were obtained between the observed spectra and the simulated ones. The lifetimes of intcrmediate species were determined from the linewidth analyses.

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